A Cavity‐Tailored Metal‐Organic Cage Entraps Gases Selectively in Solution and the Amorphous Solid State
نویسندگان
چکیده
A Zn4L4 coordination cage enabled entrapment of gases in both solution and the amorphous solid state at atmospheric pressure. The lipophilic cavity was designed through a cavity-filling strategy, which could bind small hydrocarbon gases. contrasting selectivity gas capture observed state, showing potential to be engineered as porous liquids or adsorbents for separation.
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ژورنال
عنوان ژورنال: Angewandte Chemie
سال: 2021
ISSN: ['1521-3773', '1433-7851', '0570-0833']
DOI: https://doi.org/10.1002/ange.202102095